General Information | |||||||||||||||||||||||||||||||||||||||||||
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Varieties/Types: | Blue John - A banded white/purple variety of Fluorite from England. | ||||||||||||||||||||||||||||||||||||||||||
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Chemical Formula |
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Fluorite Treatments | |||||||||||||||||||||||||||||||||||||||||||
The blue to deep blue to black color seen in some fluorites is derived from a color center, the F-center. This involves an electron-center precursor, and a missing fluorine atom in the fluorite, CaF2. An electron liberated by irradiation or other processes (Nassau, 1983) from a hole-center precursor can be trapped at the fluorine vacancy to become the electron color-center. Many other color-centers are known in fluorite, including those producing yellow, green, violet, pink, and other colors; some of these are stable to light, others are not. The color of most of these color centers can be lightened by a gentle heating to 100-150°C and is totally removed at 200-300°C. This process has long been used to lighten some excessively dark blue john, a deep blue, banded massive fluorite found in Derbyshire, England, and used for carved ornamental objects. Although colored impregnation and dyeing do not seem to have been reported, their use on massive fluorite would not be too surprising. Plastic impregnation is detected by careful examination; the heat and irradiation treatments are not identifiable - Nassau (1984) Artificial irradiation of some colorless to pale green fluorite produces a typical "iolite blue", "tanzanite", "purplish-blue", also dark blue, dark green and bright purple - Blue Chart Gem Identification, Herve Nicolas Lazzarelli, 2010, p 9 | |||||||||||||||||||||||||||||||||||||||||||
Synthetic Fluorite | |||||||||||||||||||||||||||||||||||||||||||
Synthetic fluorite in all colours is known. - Gemstones of the world, Walter Schumann, 2001, p 198 | |||||||||||||||||||||||||||||||||||||||||||
Physical Properties of Fluorite | |||||||||||||||||||||||||||||||||||||||||||
Mohs Hardness | 4Blue Chart Gem Identification (2010) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Specific Gravity | 3.00 to 3.25Blue Chart Gem Identification (2010) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Tenacity | BrittleGemstones (2009) , | ||||||||||||||||||||||||||||||||||||||||||
Cleavage Quality | PerfectBlue Chart Gem Identification (2010) , Perfect and easyMore from other references | ||||||||||||||||||||||||||||||||||||||||||
Fracture | ConchoidalGemstones of the world (2001) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Optical Properties of Fluorite | |||||||||||||||||||||||||||||||||||||||||||
Refractive Index | 1.432 to 1.436Blue Chart Gem Identification (2010) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Optical Character | IsotropicGemmological Tables (2004) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Birefringence | NoneGemstones of the world (2001) , | ||||||||||||||||||||||||||||||||||||||||||
Pleochroism | AbsentGemstones of the world (2001) , | ||||||||||||||||||||||||||||||||||||||||||
Dispersion | 0.007Gemstones of the world (2001) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Colour | |||||||||||||||||||||||||||||||||||||||||||
Colour (General) | Colourless, pink, red, brown, green, yellow, blue, violet. Colour change: blue/violet, smoky brown/lilacGemmological Tables (2004) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Colour (Daylight) | Smoky-brown (from India)Gems, Sixth Edition (2006) , | ||||||||||||||||||||||||||||||||||||||||||
Colour (Incandescent Light) | Mauve (from India)Gems, Sixth Edition (2006) , | ||||||||||||||||||||||||||||||||||||||||||
Causes of Colour | Violet, Mie scattering on calcium microcrystallites. Blue Y3+ + F vacancy +2 electrons. "Emerald" green ("chrome fluorite"), Sm2+. Yellowish green, color center containing Y3+ and Ce associated with an F vacancy. Yellow, O3 color center = O2 substituting for fluorite. Pink, YO2 color center (Y3 + O3-2). Color change, Y3+ associated color center and Sm2+, with minor influence of a Ce3+ associated color centerPragmatic Spectroscopy For Gemologists (2011) , | ||||||||||||||||||||||||||||||||||||||||||
Transparency | Transparent,Translucent,OpaqueGemmological Tables (2004) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Lustre | VitreousGemstones (2009) , | ||||||||||||||||||||||||||||||||||||||||||
Fluorescence & other light emissions | |||||||||||||||||||||||||||||||||||||||||||
Fluorescence (General) | Commonly blue to violet or greenGemmological Tables (2004) , | ||||||||||||||||||||||||||||||||||||||||||
Fluorescence (Long-Wave UV) | Inert to strong blue to greenBlue Chart Gem Identification (2010) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Phosphorescence | Some specimens phosphoresceGems, Sixth Edition (2006) , | ||||||||||||||||||||||||||||||||||||||||||
Triboluminescence | May show triboluminescenceGems, Sixth Edition (2006) , | ||||||||||||||||||||||||||||||||||||||||||
Thermoluminescence | May show thermoluminescenceGems, Sixth Edition (2006) , | ||||||||||||||||||||||||||||||||||||||||||
Crystallography of Fluorite | |||||||||||||||||||||||||||||||||||||||||||
Crystal System | IsometricBlue Chart Gem Identification (2010) , More from other references | ||||||||||||||||||||||||||||||||||||||||||
Habit | Cubic, massiveGemstones (2009) , | ||||||||||||||||||||||||||||||||||||||||||
Geological Environment | |||||||||||||||||||||||||||||||||||||||||||
Where found: | Fluorite occurs in low-to-high temperature hydrothermal veins, granites and granite pegmatitesGems, Sixth Edition (2006) , | ||||||||||||||||||||||||||||||||||||||||||
Inclusions in Fluorite | |||||||||||||||||||||||||||||||||||||||||||
Negative crystals, two- or three-phase inclusions, healing cracks, crystal inclusions - Gemmological Tables, Ulrich Henn and Claudio C. Milisenda, 2004, p 1 | |||||||||||||||||||||||||||||||||||||||||||
Further Information | |||||||||||||||||||||||||||||||||||||||||||
Mineral information: | Fluorite information at mindat.org | ||||||||||||||||||||||||||||||||||||||||||
Significant Gem Localities | |||||||||||||||||||||||||||||||||||||||||||
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